研究成果
我们团队的研究工作主要聚集于非过渡金属催化的C(sp3)-H键活化，该方法的特点是不需要过渡金属作为催化剂，无需导向基团的参与，具有高的原子的经济性和氧化还原中性的特点，是一种特别绿色的合成方法，尤其适合合成氮杂环化合物。
在这个领域，我们已经取得了一系列的研究成果，更多的研究成果已经在路上了。。。
(1)
Liang Wang, Jian Xiao,
Advancement in Cascade [1,n]-Hydrogen Transfer/Cyclization: A Method
for Direct Functionalization of Inactive C(sp3)-H Bonds，Adv.
Syn. Catal., 2014, 356(6): 1137~1171
(2)
Liang Wang，Jian
Xiao，C(sp3)–H
bond functionalization by sequential hydride transfer/cyclization:
Electronic effect and steric effect controlled regioselectivity,
Org. Chem. Front.，2016，3(5):
635~638
(3)
Mingyan Xiao，Shuai
Zhu，Yaobin
Shen，Liang
Wang*,
Jian Xiao*, Construction of Chiral Cyclic Compounds via Asymmetric
Cascade [1,n]-Hydride Transfer/Cyclization,
Chin. J. Org. Chem.
2018,
38(2): 328-340,
(4)
Liang Wang, Jian Xiao, Hydrogen-Atom Transfer Reactions,
Top. Curr. Chem.
2016, 374, 17.
(5)
Shuai Zhu, Chunqi Chen, Mingyan Xiao, Liping Yu,
Liang Wang*, Jian Xiao*,
Construction of the Tetrahydroquinoline Spiro Skeleton via Cascade
[1,5]-Hydride Transfer-involved C(sp3)-H
Functionalization “on Water”,
Green Chem., 2017,
19(23): 5653.
(7)
Chunqi Chen, Lubin Xu, Liang
Wang*,
Shuai-Shuai Li*, Efficient construction of
tetrahydroquinolines via fluorinated alcohol mediated cascade
[1,5]-hydride transfer/cyclization,
Org. Biomol. Chem.
2018, 16, 7109–7114.
(9) Lubin Xu, Pengfei Yang, Liang Wang*, Direct functionalization of benzylic and nonbenzylic C(sp3)–H bonds via keteniminium ion initiated cascade [1,5]-hydrogen transfer/cyclization, Org. Chem. Front., 2018, 5, 1854–1858.