课题组在JACS接收一篇Communication文章
2018.09.04 浏览数：0
题目：Benzotrithiophene-based Covalent Organic Frameworks: Construction and Structure Transformation under Ionothermal Condition
第一作者：Hongtao Wei(魏红涛), Jing Ning（宁静）, Xingdi Cao（曹兴弟）
通讯作者：Long Hao（郝龙）
单位：College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University （betway必威西汉姆联官网 必威）
文章网址: http://dx.doi.org/10.1021/jacs.8b08282 DOI：10.1021/jacs.8b08282
摘要：A C3-symmetric benzotrithiophene tricarbaldehyde (BTT) is synthesized for the first time with a facile method, which is used to construct BTT-based covalent organic frameworks (COFs) with different pore sizes. Meanwhile,the structure transformations of the COFs under high-temperature ionothermal condition are studied systematically, and the relationships between the regularly changed structures of the further-crosslinked COFs and their supercapacitor performances are investigated. It turns out that dealing COFs of designated structures under ionothermal condition is a great method to build high-conductive structure-controllable materials for electrochemical applications.
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第一作者：Hongtao Wei(魏红涛), Jing Ning（宁静）, Xingdi Cao（曹兴弟）
通讯作者：Long Hao（郝龙）
单位：College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University （betway必威西汉姆联官网 必威）
文章网址: http://dx.doi.org/10.1021/jacs.8b08282 DOI：10.1021/jacs.8b08282
摘要：A C3-symmetric benzotrithiophene tricarbaldehyde (BTT) is synthesized for the first time with a facile method, which is used to construct BTT-based covalent organic frameworks (COFs) with different pore sizes. Meanwhile,the structure transformations of the COFs under high-temperature ionothermal condition are studied systematically, and the relationships between the regularly changed structures of the further-crosslinked COFs and their supercapacitor performances are investigated. It turns out that dealing COFs of designated structures under ionothermal condition is a great method to build high-conductive structure-controllable materials for electrochemical applications.
PDF全文：
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